microgel systems Multiple dynamic regimes in concentrated

نویسندگان

  • David A. Sessoms
  • Irmgard Bischofberger
  • Luca Cipelletti
  • Véronique Trappe
  • DAVID A. SESSOMS
  • IRMGARD BISCHOFBERGER
  • LUCA CIPELLETTI
چکیده

Supplementary data 367.1909.5013.DC1.html http://rsta.royalsocietypublishing.org/content/suppl/2009/11/16/ "Audio Supplement" References l.html#ref-list-1 http://rsta.royalsocietypublishing.org/content/367/1909/5013.ful This article cites 27 articles, 1 of which can be accessed free Rapid response 1909/5013 http://rsta.royalsocietypublishing.org/letters/submit/roypta;367/ Respond to this article Subject collections (14 articles) optics • collections Articles on similar topics can be found in the following

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ar X iv : 0 90 7 . 23 29 v 2 [ co nd - m at . s of t ] 3 0 M ay 2 01 1 Multiple dynamic regimes in concentrated microgel systems

We investigate dynamical heterogeneities in the collective relaxation of a concentrated microgel system, for which the packing fraction can be conveniently varied by changing the temperature. The packing fraction dependent mechanical properties are characterised by a fluid-solid transition, where the system properties switch from a viscous to an elastic low-frequency behaviour. Approaching this...

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ar X iv : 0 90 7 . 23 29 v 1 [ co nd - m at . s of t ] 1 4 Ju l 2 00 9 Multiple dynamic regimes in concentrated microgel systems

We investigate dynamical heterogeneities in the collective relaxation of a concentrated microgel system, for which the packing fraction can be conveniently varied by changing the temperature. The packing fraction dependent mechanical properties are characterised by a fluid-solid transition, where the system properties switch from a viscous to an elastic low-frequency behaviour. Approaching this...

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Multiple dynamic regimes in concentrated microgel systems.

We investigate dynamical heterogeneities in the collective relaxation of a concentrated microgel system, for which the packing fraction can be conveniently varied by changing the temperature. The packing fraction-dependent mechanical properties are characterized by a fluid-solid transition, where the system properties switch from a viscous to an elastic low-frequency behaviour. Approaching this...

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Crystal structure of highly concentrated, ionic microgel suspensions studied by neutron scattering.

We present a neutron-scattering investigation of the crystal structure formed by pH -sensitive poly(2-vinylpyridine) microgel particles with 5 wt % of cross-linker. We focus on highly swollen particles and explore concentrations ranging from below close packing to well above close packing, where the particles are forced to shrink and/or interpenetrate. The crystal structure is found to be rando...

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Self‐Regulated and Temporal Control of a “Breathing” Microgel Mediated by Enzymatic Reaction

Naturally occurring systems have the ability to self-regulate, which plays a key role in their structural and functional adaptation. The autonomous behavior in living systems is biocatalytically controlled by the continuous consumption of energy to remain in a non-equilibrium condition. In this work, we show the construction of a self-regulated "breathing" microgel that uses chemical fuels to k...

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تاریخ انتشار 2009